Organosilicon compounds

被引：0
|
作者：
Hiyama, T [1 ]
Shirakawa, E
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan
[2] Japan Adv Inst Sci & Technol, Tatsunokuchi, Ishikawa 9231292, Japan
来源：
CROSS-COUPLING REACTIONS: A PRACTICAL GUIDE | 2002年 / 219卷
关键词：
palladium catalyst; organosilicate; fluoride ion; functional group tolerance;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Oraganosilicon compounds react with a wide variety of organic electrophiles in the presence of a palladium catalyst and a Lewis base activator such as a fluoride or hydroxy ion to give the corresponding coupled products. The reaction is applicable to synthesis of diynes, enynes, arylacetylenes, alkenylarenes, biaryls, allylarenes and alkylarenes in addition to 1,3-,1,4- and 1,5-dienes with tolerance for various functional groups.
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页码：61 / 85
页数：25
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