Epoxidation of 1,4-bis(allyloxy)butane by hydrogen peroxide using phase transfer catalysis

被引：10
|
作者：
Kaczmarczyk, E [1 ]
Janus, E [1 ]
Milchert, E [1 ]
机构：
[1] Tech Univ Szczecin, Inst Organ Chem Technol, PL-70322 Szczecin, Poland
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 244卷 / 1-2期
关键词：
epoxidation; hydrogen peroxide; phase transfer catalysis; epoxy-ethers;
D O I：
10.1016/j.molcata.2005.09.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Epoxidation of 1,4-bis(allyloxy)butane by hydrogen peroxide under phase transfer catalysis and transition metal salts was investigated. The most advantageous conditions for the epoxidation were determined (temperature, reaction time, the type and amount of phase transfer catalyst, molar ratio of hydrogen peroxide to 1,4-bis(allyloxy)butane, the amount and molar ratio of H3PO4:Na2WO4 center dot 2H(2)O). The process was evaluated in terms of the conversion of 1,4-bis(allyloxy)butane, hydrogen peroxide and the yields of monoepoxide and diepoxide. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：173 / 178
页数：6
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