OCTAFLUORO[2.2]PARACYCLOPHANE (AF4) QUINONE

被引：0
|
作者：
Xu, Wei [1 ]
Dolbier, William R., Jr. [1 ]
Duan, Jian-Xin [1 ]
Zhai, Yian [1 ]
Ogawa, Katsu [1 ]
Battiste, Merle A. [1 ]
Ghiviriga, Ion [1 ]
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2008年 / 73卷 / 12期
基金：
美国国家科学基金会;
关键词：
Cyclophane; Fluorinated compounds; Oxidations; 2.2]Paracyclophane; Quinones; Cyclic voltammetry; UV spectra; Diels-Alder reaction;
D O I：
10.1135/cccc20081764
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Octafluoro[2.2]paracyclophane (AF4) has been oxidized by treatment with HIO3 in CF3CO2H to form the corresponding p-quinone along with a unique triketone. This quinone undergoes reduction to the respective hydroquinone as well as a Diels-Alder reaction with 1,3-cyclohexadiene. Its reduction potential was obtained by cyclic voltammetry and is discussed in the context of other quinones.
引用
收藏
页码：1764 / 1776
页数：13
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