Study on uniaxial elongational viscosity and vacuum molding processability of the PP/PE blends

被引:3
|
作者
Shiromoto, S
Miyazawa, T
Koyama, K
机构
[1] Sumitomo Mitsui Polyolefin Co Ltd, Proc Technol Dev Grp, Sodegaura, Chiba 2990295, Japan
[2] Yamagata Univ, Dept Polymer Sci & Engn, Yonezawa, Yamagata 9928510, Japan
关键词
uniaxial elongational viscosity; strain hardening; morphology; vacuum molding;
D O I
10.1678/rheology.31.321
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
The relationship between uniaxial elongational viscosity and vacuum molding processability of the PP/PE blends were investigated. Propylene homo-polymer (PP) and 3 kinds of high pressure method low density polyethylene with different molecular weight (PE-A, PE-B, PE-C) were used. Materials were melt blended to the ratio of PP/PE=90/10, 80/20 and 70/30wt% for the experiments. The PP/PE blends showed strain hardening of uniaxial elongational viscosity, while PP showed no strain hardening. The strain hardening of PP/PE increased with increasing of the blend ratio of PE to PP, and the molecular weight of PE. The morphologies of PP/PE under uniaxial elongational flow were observed by TEM. For the samples with the lower molecular weight PE, the larger deformation of PE domain Was observed. The deviation of thickness of the vacuum Molding products decreased according to the increase of the strain hardening of PP/PE.
引用
收藏
页码:321 / 327
页数:7
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