Ge(ii) cation catalyzed hydroboration of aldehydes and ketones

被引：33
|
作者：
Sinhababu, Soumen [1 ]
Singh, Dharmendra [1 ]
Sharma, Mahendra Kumar [1 ]
Siwatch, Rahul Kumar [1 ]
Mahawar, Pritam [1 ]
Nagendran, Selvarajan [1 ]
机构：
[1] Indian Inst Technol Delhi, Dept Chem, Hauz Khas, New Delhi 110016, India
来源：
DALTON TRANSACTIONS | 2019年 / 48卷 / 13期
关键词：
ALUMINUM-HYDRIDE; CARBONYL; GERMANIUM(II); COMPLEXES; GERMYLENE; STABILIZATION; ACTIVATION; REACTIVITY; SIGMA; ELEMENTS;
D O I：
10.1039/c8dt05121f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Well-defined germylene cations [(i-Bu)(2)ATI]GeOTf (4) and [(i-Bu)(2)ATIGe][GaCl4] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).
引用
收藏
页码：4094 / 4100
页数：7
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