Silicon-mediated Direct Conversion of Acyl Chlorides to Carbamoyl Azides or/and Tetrazolinones under Mild Conditions

被引：9
|
作者：
Salama, Tarek A. [1 ]
Elmorsy, Saad S. [1 ]
Khalil, Abdel-Galil M. [1 ]
Ismail, Mohamed A. [2 ]
机构：
[1] Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt
[2] King Faisal Univ, Coll Sci, Dept Chem, Al Hufuf 31982, Saudi Arabia
来源：
CHEMISTRY LETTERS | 2011年 / 40卷 / 10期
关键词：
ONE-POT; TRIMETHYLSILYL AZIDE; CARBONYL-COMPOUNDS; CARBOXYLIC-ACIDS; SODIUM-AZIDE; ALDEHYDES; REAGENT; ISOCYANATES; DERIVATIVES; CYCLOADDITION;
D O I：
10.1246/cl.2011.1149
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple and mild one-pot procedure for the synthesis of carbamoyl asides from acyl chlorides utilizing a combination of tetrachlorosilane and sodium aside in acetonitrile at ambient temperature is reported. Under gentle heating, 1-aryltetrazolin-5-ones were also obtained in one-pot process presumably via a [3 + 2] cycloaddition step.
引用
收藏
页码：1149 / 1151
页数：3
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