Effect of heat treatment on Au-Pd catalysts synthesized by sol immobilisation for the direct synthesis of hydrogen peroxide and benzyl alcohol oxidation

被引：61
|
作者：
Pritchard, James [1 ]
Piccinini, Marco [1 ]
Tiruvalam, Ramchandra [2 ]
He, Quian [2 ]
Dimitratos, Nikolaos [1 ]
Lopez-Sanchez, Jose A. [1 ]
Morgan, David J. [1 ]
Carley, Albert F. [1 ]
Edwards, Jennifer K. [1 ]
Kiely, Christopher J. [2 ]
Hutchings, Graham J. [1 ]
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, Wales
[2] Lehigh Univ, Dept Mat Sci & Engn, Bethlehem, PA 18015 USA
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 02期
基金：
英国工程与自然科学研究理事会;
关键词：
GOLD-PALLADIUM CATALYSTS; SELECTIVE OXIDATION; BIMETALLIC CATALYSTS; H-2; H2O2; O-2; NANOPARTICLES; OXYGEN; TEMPERATURE; GLYCEROL;
D O I：
10.1039/c2cy20234d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We have investigated the effect of heat treatment in air on Au-Pd nanoparticles supported on titania and activated carbon prepared via the immobilisation of PVA-stabilised alloy nanoparticles. The catalytic activity of the gold-palladium nanoparticles was affected by both metal and PVA loading, as well as the degree of interaction of the nanoparticles with the support. The turnover frequency numbers for benzyl alcohol and hydrogen peroxide synthesis were also sensitive to the calcination procedure employed and find a doubling of catalytic activity when using activated carbon as opposed to TiO2 as the support material. These results illustrate the importance of understanding the precise metal-support interaction of catalyst systems designed for benzyl alcohol oxidation and hydrogen peroxide synthesis.
引用
收藏
页码：308 / 317
页数：10
相关论文
共 50 条
  • [1] Direct Synthesis of Hydrogen Peroxide and Benzyl Alcohol Oxidation Using Au-Pd Catalysts Prepared by Sol Immobilization
    Pritchard, James
    Kesavan, Lokesh
    Piccinini, Marco
    He, Qian
    Tiruvalam, Ramchandra
    Dimitratos, Nikolaos
    Lopez-Sanchez, Jose A.
    Carley, Albert F.
    Edwards, Jennifer K.
    Kiely, Christopher J.
    Hutchings, Graham J.
    LANGMUIR, 2010, 26 (21) : 16568 - 16577
  • [2] Solvent-free oxidation of benzyl alcohol using Au-Pd catalysts prepared by sol immobilisation
    Dimitratos, Nikolaos
    Lopez-Sanchez, Jose Antonio
    Morgan, David
    Carley, Albert F.
    Tiruvalam, Ramchandra
    Kiely, Christopher J.
    Bethell, Donald
    Hutchings, Graham J.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (25) : 5142 - 5153
  • [3] The effect of heat treatment on the performance and structure of carbon-supported Au-Pd catalysts for the direct synthesis of hydrogen peroxide
    Edwards, Jennifer K.
    Pritchard, James
    Piccinini, Marco
    Shaw, Greg
    He, Qian
    Carley, Albert F.
    Kiely, Christopher J.
    Hutchings, Graham J.
    JOURNAL OF CATALYSIS, 2012, 292 : 227 - 238
  • [4] Formation of PdO on Au-Pd bimetallic catalysts and the effect on benzyl alcohol oxidation
    Wu, Pingping
    Cao, Yunxiang
    Zhao, Lianming
    Wang, Yue
    He, Zhengke
    Xing, Wei
    Bai, Peng
    Mintova, Svetlana
    Yan, Zifeng
    JOURNAL OF CATALYSIS, 2019, 375 : 32 - 43
  • [5] Towards quaternary alloy Au-Pd catalysts for direct synthesis of hydrogen peroxide
    Waldt, Conor T.
    Ananthaneni, Sahithi
    Rankin, Rees B.
    MATERIALS TODAY ENERGY, 2020, 16
  • [6] The Effect of Bromide Pretreatment on the Performance of Supported Au-Pd Catalysts for the Direct Synthesis of Hydrogen Peroxide
    Ntainjua N, Edwin
    Piccinini, Marco
    Pritchard, James C.
    He, Qian
    Edwards, Jennifer K.
    Carley, Albert F.
    Moulijn, Jacob A.
    Kiely, Christopher J.
    Hutchings, Graham J.
    CHEMCATCHEM, 2009, 1 (04) : 479 - 484
  • [7] Direct Synthesis of Hydrogen Peroxide Over Au-Pd Catalysts Prepared by Electroless Deposition
    Alba-Rubio, Ana C.
    Plauck, Anthony
    Stangland, Eric E.
    Mavrikakis, Manos
    Dumesic, James A.
    CATALYSIS LETTERS, 2015, 145 (12) : 2057 - 2065
  • [8] The effect of catalyst preparation method on the performance of supported Au-Pd catalysts for the direct synthesis of hydrogen peroxide
    Pritchard, James C.
    He, Qian
    Ntainjua, Edwin N.
    Piccinini, Marco
    Edwards, Jennifer K.
    Herzing, Andrew A.
    Carley, Albert F.
    Moulijn, Jacob A.
    Kiely, Christopher J.
    Hutchings, Graham J.
    GREEN CHEMISTRY, 2010, 12 (05) : 915 - 921
  • [9] Cinnamaldehyde hydrogenation using Au-Pd catalysts prepared by sol immobilisation
    Cattaneo, Stefano
    Freakley, Simon J.
    Morgan, David J.
    Sankar, Meenakshisundaram
    Dimitratos, Nikolaos
    Hutchings, Graham J.
    CATALYSIS SCIENCE & TECHNOLOGY, 2018, 8 (06) : 1677 - 1685
  • [10] Au-Pd supported nanocrystals prepared by a sol immobilisation technique as catalysts for selective chemical synthesis
    Lopez-Sanchez, Jose Antonio
    Dimitratos, Nikolaos
    Miedziak, Peter
    Ntainjua, Edwin
    Edwards, Jennifer K.
    Morgan, David
    Carley, Albert F.
    Tiruvalam, Ramchandra
    Kiely, Christopher J.
    Hutchings, Graham J.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (14) : 1921 - 1930
12345