Synthesis and photoelectric property for the fullerene complex C60Pd(Ph2PCH2CH2CH2CH2PPh2)

被引：0
|
作者：
Wu, ZY [1 ]
Deng, XS [1 ]
Lin, YS [1 ]
Cheng, DD [1 ]
Zhan, MX [1 ]
机构：
[1] Xiamen Univ, Dept Chem, Xiamen 361005, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 22卷 / 02期
关键词：
fullerene; palladium complexe; photovoltaic property;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Fullerene complexe C60Pd(Ph2PCH2CH2CH2CH2PPh2) was prepared by replacement reaction in inert atmosphere and characterized by elemental analysis, IR, electronic spectroscopy, XPS and XRD. At the same time, the properties on redox and thermostability of the product were studied. The photoltaic effect of C60Pd (Ph2PCH2CH2CH2CH2PPh2) complex on GaAs electrode formation n+n heterojunction in photoelectrochemical cell H H I was investigated. The results show that the photoelectric property of CPd(Ph2PCH2C2CH2C2PPh2) is excellent, especially in the BQ/H(2)Q redox couple mediator. The photovoltaic property of C60Pd(Ph2PCH2CH2CH2PPh2)GaAs electrode at 1 mu m for thickness of C60Pd(Ph2PCH2CH2CH2CH2PPh2) is the best, the photopotential value is up to 212 mV.
引用
收藏
页码：217 / 222
页数：6
相关论文
共 50 条
  • [1] Synthesis and photoelectric property of complexe C60Pd(Ph2PCH2CH2PPh2)
    Wu, ZY
    Yang, SG
    Lin, YS
    Cheng, DD
    Zhan, MX
    [J]. JOURNAL OF INORGANIC MATERIALS, 2005, 20 (06) : 1322 - 1328
  • [2] 富勒烯配合物C60Pd(Ph2PCH2CH2CH2CH2PPh2)的合成和光电性能
    吴振奕
    邓小双
    林永生
    程大典
    詹梦熊
    [J]. 无机化学学报, 2006, (02) : 217 - 222
  • [3] Synthesis and photovoltaic effect study for fullerene complexe C60Pd(Ph2PCH2PPh2)
    Wu, ZY
    Yang, SG
    Lin, YS
    Liu, JY
    Tian, L
    Pang, ZY
    Cheng, DD
    Zhan, MX
    [J]. CHINESE JOURNAL OF CHEMICAL PHYSICS, 2004, 17 (06) : 741 - 746
  • [4] Synthesis, characterization and properties of transition metal Pd/Pt [60]fullerene complexes containing phosphane ligands -: Crystal structure of [Pd(η2-C60){Ph2PCH2(CH2OCH2)2CH2PPh2}]
    Song, LC
    Yu, GA
    Wang, HT
    Su, FH
    Hu, QM
    Song, YL
    Gao, YC
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (04) : 866 - 871
  • [5] Synthesis of Ph(2)PCH(2)C(O)H: A reinvestigation. Molecular structure of [Ph(2)PCH(OH)CH(2)PPh(2)CH(OH)CH2]Cl-2. Compared coordinative properties of Ph(2)PCH(2)C(O)H and Ph(2)PCH(2)C(O)NMe(2)
    Matt, D
    Ziessel, R
    DeCian, A
    Fischer, J
    [J]. NEW JOURNAL OF CHEMISTRY, 1996, 20 (12) : 1257 - 1263
  • [6] REACTIONS OF 1-ALKYNES WITH TRANS-[RECL(N2)(PH2PCH2CH2PPH2)2] - PREPARATION OF THE VINYLIDENE COMPOUNDS TRANS-[RECL(=C=CH-ALKYL)(PH2PCH2CH2PPH2)2], TRANS-[RECL(=C=CH-ARYL)(PH2PCH2CH2PPH2)2] AND X-RAY STRUCTURE OF TRANS-[RECL(=C=CHPH)-(PH2PCH2CH2PPH2)2]
    POMBEIRO, AJL
    ALMEIDA, SSPR
    SILVA, MFCG
    JEFFREY, JC
    RICHARDS, RL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (12): : 2381 - 2387
  • [7] NICKEL NITROSYL COMPLEXES WITH DIPHOSPHINES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(PH2PCH2CH2PPH2)(ON)NI(MU-PH2PCH2CH2PPH2)NI(NO)(PH2PCH2CH2PPH2)][BF4]2
    DEL ZOTTO, A
    MEZZETTI, A
    NOVELLI, V
    RIGO, P
    LANFRANCHI, M
    TIRIPICCHIO, A
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03): : 1035 - 1042
  • [8] STRUCTURAL CHARACTERIZATION OF 2 HAFNIUM(IV) COMPLEXES, HFCL4(PH2PCH2CH2PPH2).2C7H8 AND HFCL4(PH2PCH2CH2CH2PPH2)
    COTTON, FA
    KIBALA, PA
    WOJTCZAK, WA
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 89 - 92
  • [9] Reactivity of mercury(II) halides with the unsymmetrical phosphorus ylide Ph2PCH2CH2PPh2=C(H)C(O)Ph:: Crystal structure of {HgI2[PPh2CH2CH2PPh2=C(H)C(O)Ph]}n
    Ebrahim, Mothi Mohamed
    Stoeckli-Evans, Helen
    Panchanatheswaran, Krishnaswamy
    [J]. POLYHEDRON, 2007, 26 (14) : 3491 - 3495
  • [10] Preparation and characterization of WCl2(Ph2PCH2CH2CH2CH2O)2
    Kim, Y
    Lee, MY
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1998, 19 (12) : 1380 - 1381
12345