Study of the Reduction Mechanism of MnO2 by Rotating Ring-Disk Electrode

被引：1

作者：

Tian Jianhua ^{[1
]}

Gu Linying ^{[1
]}

机构：

[1] Tianjin Univ, Dept Appl Chem, Tianjin 300072, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1996年 / 12卷 / 05期

关键词：

MnO2; Rotating ring-disk electrode; Cathodic reduction of MnO2;

D O I：

10.3866/PKU.WHXB19960512

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cathodic reduction mechanism of MnO2 electrode is studied by means of the rotating ring-disk electrode The mass tran sport process in the solution plays an important role in the reduction process of MnO2 electrode. The relation between I-n(-1) and omega(-1/2) is deduced as a diagnostic criterion of the reduction mechanism. The dissolution precipitation and the electron proton mechanism occur simultaneously but the relative contributions are quite different in various pH value solutions.

引用

页码：446 / 450

页数：5

共 7 条

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