Fabrication and characterization of ZnxCd1-xS nanoparticles in chitosan alginate nanocomposite films

ZnxCd1-xS nanoparticles were formed in chitosan alginate nanocomposite films using spin-coating technique. Crystal structure and size, optical properties and surface morphology were characterized by X-ray diffraction (XRD), ultraviolet visible (UV-vis), photoluminescence (PL) spectra, transmission electron microscopy (TEM) and atomic force microscopy (AFM), respectively. The ZnxCd1-xS nanoparticles have a cubic structure with an average crystal size of similar to 2 nm. With increasing Zn/Cd molar ratio, the UV vis absorption peaks shift to low-wavelength side with a slight intensity decrease. The relative emission intensity of the film may be changed regularly by variation of the ZnxCd1-xS nanoparticles composition. Surface morphology of the films containing ZnxCd1-xS nanoparticles changes with various Zn/Cd molar ratios. The film morphology goes from rough to smooth with increasing Zn/Cd, and the phase goes from bump-like shape to particle-like shape with a more uniform distribution due to the radius difference between Zn and Cd ions. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.