Multiphase Catalytic Hydrogenolysis/Hydrodeoxygenation Processes for Chemicals from Renewable Feedstocks: Kinetics, Mechanism, and Reaction Engineering

被引：32
|
作者：
Chaudhari, Raghunath V. [1 ]
Torres, Arely [1 ]
Jin, Xin [1 ]
Subramaniam, Bala [1 ]
机构：
[1] Univ Kansas, Ctr Environm Beneficial Catalysis, Dept Chem & Petr Engn, Lawrence, KS 66047 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2013年 / 52卷 / 44期
关键词：
AQUEOUS-PHASE HYDROGENOLYSIS; BIOMASS-DERIVED OIL; GLYCEROL HYDROGENOLYSIS; BIO-OIL; SULFIDED COMO/GAMMA-AL2O3; SELECTIVE HYDROGENOLYSIS; OXYGENATED HYDROCARBONS; RUTHENIUM CATALYSTS; PROPYLENE-GLYCOL; GUAIACYL GROUPS;
D O I：
10.1021/ie400709d
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A review of multiphase catalytic processes in biomass conversion is presented, with an emphasis on the underlying kinetics, mechanism, and reaction engineering aspects. The distinguishing features and current state of development of catalysts and processes for a few selected examples of biomass conversion are presented, including hydrogenolysis and tandem reforming/hydrogenolysis of polyols to glycols and linear alcohols, hydrodeoxygenation of bio-oils, and polyols conversion to lactic acid along with possible reaction pathways. The complexities of multistep and multiphase catalytic reactions and kinetics modeling associated with hydrogenolysis and hydrodeoxygenation are discussed with a brief overview of reaction engineering aspects.
引用
收藏
页码：15226 / 15243
页数：18
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