Application of Sugar-Based Phosphorus Ligands in Asymmetric Hydrogenation

被引:2
|
作者
Cui, Penglei [1 ]
Liu, Huimin [1 ]
Guo, Xiumin [1 ]
Zhang, Dongnuan [1 ]
Wang, Yanen [1 ]
Wang, Chun [1 ]
机构
[1] Agr Univ Hebei, Coll Sci, Baoding 071001, Peoples R China
关键词
asymmetric hydrogenation; sugar; chiral ligand; CATALYZED ENANTIOSELECTIVE HYDROGENATION; AMINO-ACID PRECURSORS; CHIRAL LIGANDS; DIPHOSPHITE LIGANDS; RHODIUM COMPLEXES; CARBOHYDRATE PHOSPHINITES; MONOPHOSPHITE LIGANDS; REMOTE STEREOCENTERS; SUITABLE LIGANDS; D-GLUCOSE;
D O I
10.6023/cjoc201209021
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
There is a very important application for the asymmetric hydrogenation in the actual industrial production. Sugar is chiral natural product which widely exists in the nature. More and more attention was paid to the research of the chiral sugar's synthesis and application. Sugar derivatives, as chiral ligands, were widely used in asymmetric reactions and the relative research became a very active area in organic chemistry. The recent progress of sugar-based phosphorus-containing ligands that used in asymmetric hydrogenation is reviewed.
引用
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页码:436 / 443
页数:8
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