Controlling the flexibility and single-crystal to single-crystal interpenetration reconstitution of metal-organic frameworks

被引：31

作者：

Zhou, Dong-Dong ^{[1
]}

Liu, Zhi-Juan ^{[1
]}

He, Chun-Ting ^{[1
]}

Liao, Pei-Qin ^{[1
]}

Zhou, Hao-Long ^{[1
]}

Zhong, Zhen-Song ^{[1
]}

Lin, Rui-Biao ^{[1
]}

Zhang, Wei-Xiong ^{[1
]}

Zhang, Jie-Peng ^{[1
]}

Chen, Xiao-Ming ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 63期

关键词：

STRUCTURAL TRANSFORMATIONS; COORDINATION POLYMERS; EXCHANGE; LIGAND; TEMPERATURE; SORPTION; NETWORK; REARRANGEMENT; SELECTIVITY; MECHANISM;

D O I：

10.1039/c5cc05036g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By changing the ligand substituent groups near the open metal sites from hydrophilic to hydrophobic, the guest-induced structural dynamism of a series of isostructural 5-fold interpenetrated MOFs changed from interpenetration reconstitution to simple framework breathing.

引用

页码：12665 / 12668

页数：4

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