Production of Dimethylfuran from Hydroxymethylfurfural through Catalytic Transfer Hydrogenation with Ruthenium Supported on Carbon

被引：245
|
作者：
Jae, Jungho [1 ]
Zheng, Weiqing [1 ]
Lobo, Raul F. [1 ]
Vlachos, Dionisios G. [1 ]
机构：
[1] Univ Delaware, Dept Chem & Biomol Engn, Catalysis Ctr Energy Innovat, Newark, DE 19716 USA
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 07期
关键词：
alcohols; biofuels; biomass; hydrogenolysis; transfer hydrogenation; LIQUID FUELS; BIOMASS; HYDROGENOLYSIS; 2-METHYLFURAN; KINETICS;
D O I：
10.1002/cssc.201300288
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
RuCees' transfer: Transfer hydrogenation using alcohols as hydrogen donors and supported ruthenium catalysts results in the selective conversion of hydroxymethylfurfural to dimethylfuran (>80 % yield). During transfer hydrogenation, the hydrogen produced from alcohols is utilized in the hydrogenation of hydroxymethylfurfural. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1158 / 1162
页数：5
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