Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations

被引：54

作者：

Jia, Fei ^{[1
,2
,3
]}

Hupatz, Henrik ^{[1
]}

Yang, Liu-Pan ^{[2
,3
]}

Schroder, Hendrik, V ^{[1
]}

Li, Dong-Hao ^{[2
,3
]}

Xing, Shan ^{[2
,3
]}

Lentz, Dieter ^{[4
]}

Witte, Felix ^{[1
]}

Xie, Xiaojiang ^{[2
,3
]}

Paulus, Beate ^{[1
]}

Schalley, Christoph A. ^{[1
]}

Jiang, Wei ^{[2
,3
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, Takustr 3, D-14195 Berlin, Germany

[2] Southern Univ Sci & Technol, Dept Chem, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China

[3] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Xueyuan Blvd 1088, Shenzhen 518055, Peoples R China

[4] Free Univ Berlin, Inst Chem & Biochem, Fabeckstr 34-36, D-14195 Berlin, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 10期

基金：

中国国家自然科学基金;

关键词：

BINDING; RECOGNITION; LIGAND;

D O I：

10.1021/jacs.9b00445

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a quite flexible naphthol-based cage (so-called "naphthocage") which adopts a self-inclusion conformation in its free state and is able to bind singly charged organic cations extremely strongly (K-a > 10(7) M-1). Ion-selective electrodes prepared with this naphthocage show a super-Nernstian response to acetylcholine. In addition, the highly stable complex (10(10) M-1) between ferrocenium and the naphthocage can be switched electrochemically, which lays a basis for its application in stimuli-responsive materials.

引用

页码：4468 / 4473

页数：6

共 2 条

[1] Electron-Induced Dissociation of Singly Charged Organic Cations as a Tool for Structural Characterization of Pharmaceutical Type Molecules
Mosely, Jackie A.
Smith, Michael J. P.
Prakash, Aruna S.
Sims, Martin
Bristow, Anthony W. T.
[J]. ANALYTICAL CHEMISTRY, 2011, 83 (11) : 4068 - 4075
[2] ION-EXCHANGE SORPTION OF SINGLY CHARGED ORGANIC CATIONS ON CROSS-LINKED CARBOXYLIC CATION-EXCHANGERS
PISAREV, OA
SHATAEVA, LK
SAMSONOV, GV
[J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1980, 29 (01): : 29 - 33

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