Phosphor coated NiO-based planar inverted organometallic halide perovskite solar cells with enhanced efficiency and stability

被引:30
|
作者
Cui, Jin [1 ]
Li, Pengfei [2 ]
Chen, Zhifan [1 ]
Cao, Kun [1 ]
Li, Dan [1 ]
Han, Junbo [3 ]
Shen, Yan [1 ]
Peng, Mingying [2 ]
Fu, Yong Qing [4 ]
Wang, Mingkui [1 ]
机构
[1] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Sch Opt & Elect Informat, Wuhan 430074, Hubei, Peoples R China
[2] South China Univ Technol, Sch Mat Sci & Engn, China Germany Res Ctr Photon Mat & Device, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Peoples R China
[3] Huazhong Univ Sci & Technol, Wuhan Natl High Magnet Field Ctr, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China
[4] Northumbria Univ, Fac Engn & Environm, Dept Phys & Elect Engn, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England
基金
中国国家自然科学基金;
关键词
LIFE-CYCLE ASSESSMENT; CH3NH3PBI3; PEROVSKITE; TRANSPORT LAYERS; STATE; OXIDE; PHOTOVOLTAICS; ENERGY; FILMS; TIO2; AIR;
D O I
10.1063/1.4965838
中图分类号
O59 [应用物理学];
学科分类号
摘要
This work investigates non-rare-earth phosphor (Sr4Al14O25:Mn4+, 0.5%Mg) with intensively red luminescence as a luminescent down-shifting layer for perovskite solar cells. The power conversion efficiency of the fabricated device with a structure of NiO/CH3NH3PbI3/[6,6]-phenyl C-61-butyric acid methyl ester/Au coated with phosphor layer shows a 10% increase as compared with that of the control devices. Importantly, the phosphor layer coating can realize UV-protection as well as waterproof capability, achieving a reduced moisture-degradation of CH3NH3PbI3 perovskite upon applying an UV irradiation. Therefore, perovskite devices using this luminescent coating show a combined enhancement in both UV down-shifting conversion and long term stability. This can be expanded as a promising encapsulation technique in the perovskite solar cell community. Published by AIP Publishing.
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页数:5
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