One-dimensional N2 gas inside single-walled carbon nanotubes

被引：16

作者：

Kramberger, Christian ^{[1
]}

Thurakitseree, Theerapol ^{[1
]}

Koh, Heeyuen ^{[1
]}

Izumi, Yudai ^{[2
]}

Kinoshita, Toyohiko ^{[2
]}

Muro, Takayuki ^{[2
]}

Einarsson, Erik ^{[1
]}

Maruyama, Shigeo ^{[1
]}

机构：

[1] Univ Tokyo, Dept Mech Engn, Bunkyo Ku, Tokyo 1138656, Japan

[2] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan

来源：

CARBON | 2013年 / 55卷

关键词：

PHOTOCHEMISTRY BEAMLINE BL27SU; MOLECULAR-DYNAMICS; CNX NANOTUBES; ENCAPSULATION; NITROGEN; SPRING-8;

D O I：

10.1016/j.carbon.2012.12.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The unexpected presence of a linear arrangement of co-axially oriented N-2 molecules inside aligned single-walled carbon nanotubes is revealed by high resolution near-edge X-ray absorption spectroscopy. The encapsulated N-2 molecules exhibit free stretching vibrations with a long electronic lifetime of the X-ray-excited anti-bonding pi* states. Molecular dynamics simulations confirm that narrow-diameter nanotubes (d < 1 nm) are crucial for stabilizing the linear arrangement of aligned N-2 molecules. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：196 / 201

页数：6

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