Naphthalenediimide (NDI) polymers for all-polymer photovoltaics

被引:168
|
作者
Zhou, Nanjia [1 ]
Facchetti, Antonio [2 ,3 ]
机构
[1] Natl Univ Singapore, EA-07-08,9 Engn Dr 1, Singapore 117575, Singapore
[2] Northwestern Univ, 2145 Sheridan Rd, Evanston, IL 60208 USA
[3] Flexterra Corp, 8025 Lamon Ave, Skokie, IL 60077 USA
关键词
ORGANIC SOLAR-CELLS; POWER CONVERSION EFFICIENCY; FIELD-EFFECT TRANSISTORS; OPEN-CIRCUIT VOLTAGE; N-TYPE POLYMERS; D-A COPOLYMERS; HIGH-PERFORMANCE; FULLERENE-POLYMER; MOLECULAR-WEIGHT; CONJUGATED POLYMERS;
D O I
10.1016/j.mattod.2018.02.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Naphthalenediimide (NDI) polymers are an important class of electron-accepting (acceptor or n-type) semiconductors for organic photovoltaic (OPV) or organic solar cell (OSC) applications. Blending them with compatible electron-donating (donor or p-type) polymers yields an OPV device known as bulk-heterojunction (BHJ) all-polymer solar cells (all-PSCs). Compared to the more extensively studied OPVs using fullerene derivatives as the acceptor material, all-PSCs provide important benefits such as chemical tunability, mechanical flexibility and ambient/stress stability. Through an extensive research on materials design and device optimization in the last five years, all-PSCs employing NDI-based polymers have achieved remarkable improvement in device power conversion efficiency (PCE), now surpassing 10% - a number that approaches the state-of-the-art organic photovoltaic (OPV) cells using fullerenes. In this review, recent development of NDI-based conjugated polymers used in all-PSCs will be highlighted.
引用
收藏
页码:377 / 390
页数:14
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