Relationship between two-photon absorption and the π-conjugation pathway in porphyrin arrays through dihedral angle control

被引：208
|
作者：
Ahn, TK
Kim, KS
Kim, DY
Noh, SB
Aratani, N
Ikeda, C
Osuka, A [1 ]
Kim, D
机构：
[1] Kyoto Univ, JST, CREST, Dept Chem,Grad Sch Sci, Kyoto 6068502, Japan
[2] Yonsei Univ, Ctr Ultrafast Opt Characterist Control, Seoul 120749, South Korea
[3] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 05期
关键词：
D O I：
10.1021/ja056773a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recently, covalently linked or self-assembled porphyrin array systems have attracted much attention for their enhanced two-photon absorption (TPA) behaviors. In this study, we have investigated the TPA properties of various dihedral angle controlled, directly linked porphyrin dimers and arrays to elucidate the relationship between the pi-conjugation pathway and TPA properties. We have demonstrated a strong correlation between pi-conjugation (aromaticity) and TPA properties in porphyrin assemblies.
引用
收藏
页码：1700 / 1704
页数：5
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