Strong two-photon absorption and its saturation of a self-organized dimer of an ethynylene-linked porphyrin tandem

被引：23
|
作者：
Kamada, Kenji [1 ]
Hara, Chihiro [2 ]
Ogawa, Kazuya [2 ]
Ohta, Koji [1 ]
Kobuke, Yoshiaki [2 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Ubiquitous Energy Devices, Ikeda, Osaka 5638577, Japan
[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 64期
关键词：
NONLINEAR-OPTICAL PROPERTIES; PHOTOPHYSICAL PROPERTIES; EXPANDED PORPHYRINS; CROSS-SECTION; ENHANCEMENT; ARRAYS; OLIGOMERS; MODEL;
D O I：
10.1039/c2cc30879g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The two-photon absorption properties of a self-organized dimer of a free-base and zinc(II) porphyrins tandem linked with an ethynylene group and terminated by imidazolyl and phenylethynyl groups were investigated. The self-organized dimer was found to exhibit strong two-photon absorption and furthermore the saturation of the two-photon absorption owing to the intense transition.
引用
收藏
页码：7988 / 7990
页数：3
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