Cathodic reactivity of graphite with carbon dioxide: an efficient formation of carboxylated carbon materials

被引：25

作者：

Dano, C ^{[1
]}

Simonet, J ^{[1
]}

机构：

[1] Univ Rennes 1, Lab Electrochim Mol & Macromol, UMR 6510, F-35042 Rennes, France

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2004年 / 564卷 / 1-2期

关键词：

graphite; cathodic charge; graphite carboxylation; carbon modification; tetraalkylammonium salt;

D O I：

10.1016/j.jelechem.2003.10.012

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Several kinds of graphites (natural from Ceylon, highly oriented pyrolytic (HOPG), pyrolytic crystals) were cathodically charged in the presence of dimethylformamide containing 0.1 M tetraalkylammonium tetrafluoroborate. After uptake of different amounts of charge, the reduced materials were allowed to react with carbon dioxide in solution. Data on the rate of carboxylation are given and the analytical methods providing information on the modification of graphite on the surface and in the bulk. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：115 / 121

页数：7

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