Synthesis of unnatural hydroxyanthraquinones: Experiments towards total synthesis of pradimicinone

被引：0
|
作者：
Murty, KVSN [1 ]
Hazra, NK [1 ]
Datta, K [1 ]
Mal, D [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM,KHARAGPUR 721302,W BENGAL,INDIA
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1997年 / 36卷 / 02期
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The phthalide sulfone 5 has been prepared from readily available ester 6 in four steps on multigram scales. This has been utilized in anionic [4 + 2] cycloaddition with a few cyclohexenones (12-14) to obtain anthraquinones (18-26) in good yields, compound 21 being a potential intermediate for pradimicinone 1.
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页码：126 / 132
页数：7
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