Parametric study on electrochemical reforming of glycerol for hydrogen production

被引：5

作者：

Yildiz, Merve Gordesel ^{[1
,2
]}

Yoruk, Ozgu ^{[1
,2
]}

Uysal, Duygu ^{[1
,2
]}

Dogan, Ozkan Murat ^{[1
,2
]}

Uysal, Bekir Zuhtu ^{[1
,2
]}

机构：

[1] Gazi Univ, Fac Engn, Chem Engn Dept, Yukselis St, TR-06570 Ankara, Turkey

[2] Clean Energy Res & Applicat Ctr CERAC TEMENAR, Yukselis St, TR-06570 Ankara, Turkey

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2022年 / 47卷 / 95期

关键词：

Hydrogen; Biodiesel; Glycerol; Electrochemical reforming; Electrolysis; SELECTIVE ELECTROOXIDATION; WATER SOLUTIONS; MEMBRANE; OXIDATION; ETHANOL; ACID; CATALYSTS; PLATINUM; METHANOL; AU;

D O I：

10.1016/j.ijhydene.2022.03.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen production by electrochemical reforming of glycerol was investigated in this study. Within this scope, the performance of the system under different operating conditions was evaluated by parametric studies and optimum operating conditions were determined. The effects of membrane type, membrane pre-treatment procedure and temperature were investigated. System performance was examined also with long-term tests. The formation of hydrogen at the cathode was determined by analyzing the product gases by gas chromatography. Optimum condition for maximum hydrogen production was obtained with the Zn/Zn electrode pair in the presence of 0.4 M glycerol and 0.04 M H2SO4 at the anode side, 0.04 M H2SO4 at the cathode side and with pre-treated Nafion XL membrane. As the result of performance tests, room temperature and 2 V potential were found to be the most suitable operating conditions. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：40196 / 40203

页数：8

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