In situ Polymerization Technique for Obtaining Composite Materials Based on Polyethylene, Multi-walled Carbon Nanotubes and Cobalt Nanoparticles

被引:14
|
作者
Kazakova, M. A. [1 ,2 ]
Semikolenova, N. V. [1 ]
Korovin, E. Yu. [3 ]
Moseenkov, S. I. [1 ]
Andreev, A. S. [1 ]
Kachalov, A. S. [3 ]
Kuznetsov, V. L. [1 ,3 ]
Suslyaev, V. I. [3 ]
Mats'ko, M. A. [1 ]
Zakharov, V. A. [1 ]
机构
[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Tomsk State Univ, Tomsk 634050, Russia
关键词
HEAT-FLOW DSC; CALIBRATION COEFFICIENT; MICROWAVE;
D O I
10.1134/S1070427218010202
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Specific features of formation of composite materials based on polyethylene, multi-walled carbon nanotubes, and cobalt nanoparticles (MWCNT-PE and Co/MWCNT-PE) by in situ polymerization were revealed. The in situ polymerization technique is based on ethylene polymerization on a highly dispersed Ti-containing catalyst supported on the surface of MWCNT and DD 3/4 /MWCNT. This method ensures uniform distribution of MWCNT and Co/MWCNT in the polyethylene matrix. The effect of MWCNT and DD 3/4 /MWCNT on the final properties of the composite materials was determined. Introduction of MWCNT into the polyethylene matrix increases the specific electrical conductivity of the material. Such composite materials can be used for preparing concentrates with preset composition for the subsequent preparation of antistatic coatings. Introduction of the DD 3/4 /MWCNT filler into the polyethylene matrix makes the material paramagnetic owing to Co nanoparticles and allows its use for preparing coatings that efficiently protect from electromagnetic radiation.
引用
收藏
页码:127 / 135
页数:9
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