Visible-Light-Driven CO2 Reduction Catalyzed by a Dinuclear Nickel Complex

被引:7
|
作者
Wang, Jia-Wei [1 ]
Sun, Jia-Kai [1 ]
Liu, Dong-Cheng [2 ]
Jiang, Long [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem, KLGHEI Environm & Energy Chem, Guangzhou 510275, Peoples R China
[2] Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, Guilin 541004, Peoples R China
基金
中国国家自然科学基金;
关键词
CO2; reduction; Homogeneous catalyst; Nickel; Photocatalysis; CARBON-DIOXIDE; SELECTIVE REDUCTION; ELECTROCATALYST; MACROCYCLES; MONOXIDE; CYCLAM; WATER;
D O I
10.1002/ejic.202000816
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The utilization of synergy between two metal sites in dinuclear metal catalysts for CO2 reduction remains challenging. Herein, for the first time, we employ a dinuclear nickel complex as a molecular catalyst for visible-light-driven CO2 reduction with 99 % selectivity toward CO production. The photocatalytic mechanism was proposed based on the results of electrochemical measurements and fluorescent quenching experiments.
引用
收藏
页码:4450 / 4453
页数:4
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