Influence of Structural Variations in Push-Pull Zinc Porphyrins on Photovoltaic Performance of Dye-Sensitized Solar Cells

被引：33

作者：

Yi, Chenyi ^{[1
]}

Giordano, Fabrizio ^{[1
]}

Cevey-Ha, Ngoc-Le ^{[1
]}

Tsao, Hoi Nok ^{[1
]}

Zakeeruddin, Shaik M. ^{[1
]}

Graetzel, Michael ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 04期

基金：

欧洲研究理事会; 瑞士国家科学基金会;

关键词：

cobalt; dye-sensitized solar cells; porphyrins; structure-activity relationships; titanium oxide; COMPLEX REDOX SHUTTLE; ARTIFICIAL PHOTOSYNTHESIS; DESIGN; ELECTROLYTE; TRANSPORT;

D O I：

10.1002/cssc.201301271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We designed and synthesized two new zinc porphyrin dyes for dye-sensitized solar cells (DSCs). Subtle molecular structural variation in the dyes significantly influenced the performance of the DSC devices. By utilizing these dyes in combination with a cobalt-based redox electrolyte using a photoanode made of mesoporous TiO2, we achieved a power conversion efficiency (PCE) of up to 12.0% under AM1.5G (100mWcm(-2)) simulated solar light. Moreover, we obtained a high PCE of 6.4% for solid-state dye-sensitized solar cells by using 2,2,7,7-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9-spirobifluorene as a hole-transporting material.

引用

页码：1107 / 1113

页数：7

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