Alternating Ring-Opening Metathesis Polymerization Copolymers Containing Charge-Transfer Units

被引：29
|
作者：
Romulus, Joy [1 ,2 ]
Tan, Li [3 ]
Weck, Marcus [1 ,2 ]
Sampson, Nicole S. [3 ]
机构：
[1] NYU, Dept Chem, New York, NY 10003 USA
[2] NYU, Inst Mol Design, New York, NY 10003 USA
[3] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
来源：
ACS MACRO LETTERS | 2013年 / 2卷 / 08期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
ROMP; NORBORNENE;
D O I：
10.1021/mz4002673
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Alternating copolymers derived from the ring-opening metathesis polymerization (ROMP) of functionalized cyclobutene esters (CBEs) and cyclohexenes (CHs) are described. The copolymer poly(CBE-alt-CH) contains alternating side chains based on dialkoxynaphthalene (DAN) and pyromellitic dianhydride (PDI). Characterization by UV-vis spectroscopy showed that the copolymers exhibit an increase in charge-transfer intensity in comparison to previously reported alternating copolymers. The bulky side chains inhibit backbiting during the polymerization and allow for enhanced control over the polymerization in comparison to copolymers functionalized with linear alkyl groups.
引用
收藏
页码：749 / 752
页数：4
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