Early stage hydration mechanism of cellulose ether modified thin layer cement pastes

被引:6
|
作者
Ma Baoguo [1 ]
Su Lei [1 ]
Jian Shouwei [1 ]
Song Xuefeng [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Silicate Bldg Mat, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
cellulose ether; thin layer cement pastes; high water-absorbing matrix; hydration products; POLYMERS; WATER;
D O I
10.1007/s11595-012-0624-y
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The early stage hydration mechanism of cellulose ether modified thin layer cement pastes was studied, using brick as the matrix. Samples of 6 h, 24 h, and 3 d and 7 d hydration time were analyzed to study the hydration law on the surface of high water-absorbing matrix. Hydration products were qualitatively and semi-quantitatively analyzed using XRD, TG-DSC-DTG, FTIR and SEM. The experimental results show that there is no enough water for 2 mm thick cement pastes to hydrate, because of rapid water absorption of matrix. Trace amounts of Ca (OH)(2) was detected after three days hydration. With the prolongation of hydration time, the category and concentration of hydration products do not change. Compared with 2 mm thick cement pastes, 6 mm thick cement pastes and 10 mm thick cement pastes have lower dehydration rate and water loss. The humidity field of the cement paste show different changes within the same time. 6 mm thick cement paste and 10 mm thick cement pastes have longer time and more water to hydrate. Ca(OH)(2) and ettringite were detected after 6 hours hydration and the concentrations of hydration products increased from 24 hours to 7 days.
引用
收藏
页码:1172 / 1176
页数:5
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