Eldfellite, NaFe(SO4)2: an intercalation cathode host for low-cost Na-ion batteries

被引：181
|
作者：
Singh, Preetam [1 ]
Shiva, Konda
Celio, Hugo
Goodenough, John B.
机构：
[1] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2015年 / 8卷 / 10期
关键词：
ELECTRODE MATERIALS; RECHARGEABLE BATTERIES; LITHIUM INTERCALATION; SODIUM BATTERY; INSERTION; SULFATE;
D O I：
10.1039/c5ee02274f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The mineral eldfellite, NaFe(SO4)(2), is characterized as a potential cathode for a Na-ion battery that is fabricated in charged state; its 3 V discharge versus sodium for reversible Na+ intercalation is shown to have a better capacity, but lower insertion rate than Li+ intercalation. The theoretical specific capacity for Na+ insertion is 99 mA h g(-1). After 80 cycles at 0.1C versus a Na anode, the specific capacity was 78 mA h g(-1) with a coulomb efficiency approaching 100%.
引用
收藏
页码：3000 / 3005
页数：6
相关论文
共 50 条
  • [1] Eldfellite NaV(SO4)2 as a versatile cathode insertion host for Li-ion and Na-ion batteries
    Singh, Shashwat
    Singh, Deobrat
    Ahuja, Rajeev
    Fichtner, Maximilian
    Barpanda, Prabeer
    JOURNAL OF MATERIALS CHEMISTRY A, 2023, 11 (08) : 3975 - 3986
  • [2] Eldfellite-type cathode material, NaV(SO4)2, for Na-ion batteries
    Nishio, Akira
    Ishado, Yuji
    Nakamoto, Kosuke
    Kobayashi, Eiichi
    Inoishi, Atsushi
    Sakaebe, Hikari
    Okada, Shigeto
    MATERIALS ADVANCES, 2022, 3 (18): : 6993 - 7001
  • [3] NaFe2PO4(SO4)2: a potential cathode for a Na-ion battery
    Shiva, Konda
    Singh, Preetam
    Zhou, Weidong
    Goodenough, John B.
    ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (10) : 3103 - 3106
  • [4] Eldfellite-structured NaCr(SO4)2: a potential anode for rechargeable Na-ion and Li-ion batteries
    Kumar, Saurabh
    Mondal, Rakesh
    Prakash, Rajiv
    Singh, Preetam
    DALTON TRANSACTIONS, 2022, 51 (31) : 11823 - 11833
  • [5] Ultrasonically assisted microwave synthesis and electronic transport properties of Eldfellite, NaFe(SO4)2, a potential cathode material for Sodium-Ion Batteries
    Salame, Paresh H.
    Devakar, Minakshi
    CERAMICS INTERNATIONAL, 2020, 46 (18) : 28844 - 28850
  • [6] A Superior Low-Cost Cathode for a Na-Ion Battery
    Wang, Long
    Lu, Yuhao
    Liu, Jue
    Xu, Maowen
    Cheng, Jinguang
    Zhang, Dawei
    Goodenough, John B.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (07) : 1964 - 1967
  • [7] Evaluation of Low-cost Natrochalcite Na[Cu2(OH)(H2O)(SO4)2] as an Anode Material for Li- and Na-ion Batteries
    Liu, Zhen
    Zhou, Huajun
    Ang, Simon S.
    Zhang, Jian-Jun
    ELECTROCHIMICA ACTA, 2016, 211 : 619 - 626
  • [8] Sodium intercalation in the phosphosulfate cathode NaFe2(PO4)(SO4)2
    Ben Yahia, Hamdi
    Essehli, Rachid
    Amin, Ruhul
    Boulahya, Khalid
    Okumura, Toyoki
    Belharouak, Ilias
    JOURNAL OF POWER SOURCES, 2018, 382 : 144 - 151
  • [9] A2VO(SO4)2 (A = Li, Na) as Electrodes for Li-Ion and Na-Ion Batteries
    Sun, Meiling
    Rousse, Gwenaelle
    Saubanere, Matthieu
    Doublet, Marie-Liesse
    Dalla Corte, Daniel
    Tarascon, Jean-Marie
    CHEMISTRY OF MATERIALS, 2016, 28 (18) : 6637 - 6643
  • [10] Enhanced electrode kinetics and electrochemical properties of low-cost NaFe2PO4(SO4)2 via Ca2+ doping as cathode material for sodium-ion batteries
    Shao-Fang Li
    Zhen-Yi Gu
    Jin-Zhi Guo
    Xian-Kun Hou
    Xu Yang
    Bo Zhao
    Xing-Long Wu
    JournalofMaterialsScience&Technology, 2021, 78 (19) : 176 - 182
12345