Efficient C-S cross coupling catalyzed by Cu2O

被引：98
|
作者：
Xu, Hua-Jian [2 ]
Zhao, Xiao-Yang [2 ]
Deng, Jin [1 ]
Fu, Yao [1 ]
Feng, Yi-Si [2 ]
机构：
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 04期
基金：
中国国家自然科学基金;
关键词：
SULFUR BOND FORMATION; ALPHA-AMINO-ACIDS; ARYL HALIDES; BORONIC ACIDS; THIOLS; COPPER; IODIDES; LIGAND; ARYLATION; THIOETHERS;
D O I：
10.1016/j.tetlet.2008.11.029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A protocol for the copper-catalyzed C-S bond formation between aryl, alkyl, or heteroaryl thiols and aryl or heteroaryl halides is reported. The reaction is catalyzed by Cu2O which shows the highest catalytic activity with ethyl 2-oxocyclohexanecarboxylate ligand in DMSO at 80 degrees C. The corresponding coupling products are obtained with good to excellent yields under relatively mild reaction conditions with good chemoselectivity and functional group tolerance. (c) 2008 Published by Elsevier Ltd.
引用
收藏
页码：434 / 437
页数：4
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