Interfacial in situ polymerization of single wall carbon nanotube/nylon 6,6 nanocomposites

被引:129
|
作者
Haggenmueller, R
Du, FM
Fischer, JE
Winey, KI
机构
[1] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] Univ Penn, Dept Chem & Biomol Engn, Philadelphia, PA 19104 USA
基金
美国国家科学基金会;
关键词
nanocomposite; single wall carbon nanotube; in situ polymerization;
D O I
10.1016/j.polymer.2006.01.087
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
An interfacial polymerization method for nylon 6,6 was adapted to produce nanocomposites with single wall carbon nanotubes (SWNT) via in situ polymerization. SWNT were incorporated in purified, functionalized or surfactant stabilized forms. The functionalization of SWNT was characterized by FTIR, Raman spectroscopy and TGA and the SWNT dispersion was characterized by optical microscopy before and after the in situ polymerization. SWNT functionalization and surfactant stabilization improved the nanotube dispersion in solvents but only functionalized SWNT showed a good dispersion in composites, whereas purified and surfactant stabilized SWNT resulted in poor dispersion and nanotube agglomeration. Weak shear flow induced SWNT flocculation in these nanocomposites. The electrical and mechanical properties of the SWNT/nylon nanocomposites are briefly discussed in terms of SWNT loading, dispersion, length and type of functionalization. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2381 / 2388
页数:8
相关论文
共 50 条
  • [1] Preparation of multiwalled carbon nanotube/nylon-6 nanocomposites by in situ polymerization
    Saeed, Khalid
    Park, Soo-Young
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 106 (06) : 3729 - 3735
  • [2] In situ Polymerization of Multi-Walled Carbon Nanotube/Nylon-6 Nanocomposites and Their Electrospun Nanofibers
    Khalid Saeed
    Soo-Young Park
    Sajjad Haider
    Jong-Beom Baek
    [J]. Nanoscale Research Letters, 4
  • [3] In situ Polymerization of Multi-Walled Carbon Nanotube/Nylon-6 Nanocomposites and Their Electrospun Nanofibers
    Saeed, Khalid
    Park, Soo-Young
    Haider, Sajjad
    Baek, Jong-Beom
    [J]. NANOSCALE RESEARCH LETTERS, 2009, 4 (01): : 39 - 46
  • [4] Fabrication of nylon 6,6 grafted graphene-carbon nanotube hybrids for the reinforcement of nylon 6,6 composites
    Kim, Muhyeon
    Kim, Dongeun
    Choi, Eun Yeop
    Kim, Chang Keun
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [5] Synthesis of exfoliated polyamide 6,6/organically modified montmorillonite nanocomposites by in situ interfacial polymerization
    Tarameshlou, M.
    Jafari, S. H.
    Khonakdar, H. A.
    Farmahini-Farahani, M.
    Ahmadian, S.
    [J]. POLYMER COMPOSITES, 2007, 28 (06) : 733 - 738
  • [6] Nylon 610 and carbon nanotube composite by in situ interfacial polymerization
    Kang, Minsung
    Myung, Seung Jun
    Jin, Hyoung-Joon
    [J]. POLYMER, 2006, 47 (11) : 3961 - 3966
  • [7] Preparation and characterization of single-walled carbon nanotube/nylon 6, 6 nanocomposites
    Saeed, Khalid
    Khan, Ibrahim
    [J]. INSTRUMENTATION SCIENCE & TECHNOLOGY, 2016, 44 (04) : 435 - 444
  • [8] Characteristics of nylon 6,6/nylon 6,6 grafted multi-walled carbon nanotube composites fabricated by reactive extrusion
    Roh, Sang Chul
    Kim, Jisun
    Kim, Chang Keun
    [J]. CARBON, 2013, 60 : 317 - 325
  • [9] Aligned carbon nanotube/nylon-6 nanocomposites
    Steinert, Brian W.
    Jose, Moncy V.
    Thomas, Vinoy
    Dean, Derrick R.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [10] Reinforcement of nylon 6,6/nylon 6,6 grafted nanodiamond composites by in situ reactive extrusion
    Eun-Yeob Choi
    Kiho Kim
    Chang-Keun Kim
    Eunah Kang
    [J]. Scientific Reports, 6