Recent advances in copper-catalyzed imine-based multicomponent reactions

被引：14
|
作者：
Innocenti, Riccardo [1 ]
Lenci, Elena [1 ]
Trabocchi, Andrea [1 ]
机构：
[1] Univ Florence, Dept Chem Ugo Schiff, Via Lastruccia 13, I-50019 Sesto Fiorentino, Italy
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 29期
关键词：
Heterocyclic chemistry; Transition metal catalysis; Coupling reactions; Imines; Mannich-type reactions; ENANTIOSELECTIVE SYNTHESIS; 3-COMPONENT REACTION; CARBONYL-COMPOUNDS; MANNICH REACTION; AMINES; PROPARGYLAMINES; EFFICIENT; ALLENES; ALKYNES; ALDEHYDES;
D O I：
10.1016/j.tetlet.2020.152083
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Multicomponent Reactions (MCRs) based on imines are experiencing a growing interest in organic chemistry, due to the availability of different aldehydes and amines, and the versatile and amenable chemical behaviour of imines. This rise in popularity is also due to the impulse given by the development of copper-catalyzed MCRs, as copper is an inexpensive and environmentally-friendly metal that can drive the addition of a third component in providing Mannich-type adducts. This digest paper covers a selection of recent advances in copper-catalyzed imine-based MCRs where the third component is an alkyne, an organoboron reagent, an allene/alkene or a cyanide. (C) 2020 Elsevier Ltd. All rights reserved.
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页数：9
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