Carbon Dioxide Capture and Use: Organic Synthesis Using Carbon Dioxide from Exhaust Gas

被引:94
|
作者
Kim, Seung Hyo [1 ,2 ,3 ]
Kim, Kwang Hee [1 ,2 ,3 ]
Hong, Soon Hyeok [1 ,2 ,3 ]
机构
[1] Inst for Basic Sci Korea, Ctr Nanoparticle Res, Seoul 151742, South Korea
[2] Seoul Natl Univ, Coll Nat Sci, Dept Chem, Seoul 151747, South Korea
[3] Korea Carbon Capture Sequestrat R&D Ctr KCRC, Taejon 305303, South Korea
关键词
carbon dioxide capture; carbon dioxide fixation; ethanolamine; renewable resources; sustainable chemistry; TERMINAL ALKYNES; CO2; CAPTURE; CYCLIC CARBONATES; SECONDARY-AMINES; ATMOSPHERIC CO2; MILD CONDITIONS; IONIC LIQUIDS; EPOXIDES; CARBOXYLATION; COPOLYMERIZATION;
D O I
10.1002/anie.201308341
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A carbon capture and use (CCU) strategy was applied to organic synthesis. Carbon dioxide (CO2) captured directly from exhaust gas was used for organic transformations as efficiently as hyper-pure CO2 gas from a commercial source, even for highly air-and moisture-sensitive reactions. The CO2 capturing aqueous ethanolamine solution could be recycled continuously without any diminished reaction efficiency.
引用
收藏
页码:771 / 774
页数:4
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