Non-Oxidative Conversion of 1,2-Dichloroethane in a Non-Thermal Plasma and Characterisation of the Polymer Formed

被引：6

作者：

Gaikwad, Vaibhav ^{[1
]}

Kennedy, Eric ^{[1
]}

Mackie, John ^{[1
]}

Holdsworth, Clovia ^{[2
]}

Molloy, Scott ^{[1
]}

Kundu, Sazal ^{[1
]}

Dlugogorski, Bogdan ^{[1
]}

机构：

[1] Univ Newcastle, Sch Engn, Proc Safety & Environm Protect Res Grp, Callaghan, NSW 2308, Australia

[2] Univ Newcastle, Sch Environm & Life Sci, Callaghan, NSW 2308, Australia

来源：

PLASMA PROCESSES AND POLYMERS | 2013年 / 10卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

dichloroethane; dielectric barrier discharge; non-oxidative treatment; polymerisation; vinyl chloride; METHANE CONVERSION; DECOMPOSITION; HYDROCARBONS; MECHANISM; HYDROGEN; KINETICS;

D O I：

10.1002/ppap.201200045

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

This paper focuses on the conversion of 1,2-dichloroethane (EDC) using non-thermal plasma under reaction conditions that can decompose EDC and yield a value-added product. A cylindrical double dielectric barrier discharge system has been used to generate non-thermal plasma and quartz has been used as a dielectric. Our findings show that under non-oxidative reaction conditions employed in this study, vinyl chloride, a commercially important compound, is the major gas phase product produced. This paper also encompasses a preliminary characterisation of polymer during the reaction. Possible mechanisms for gaseous product formation and polymerisation are presented.

引用

页码：141 / 149

页数：9

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