Mechanisms in Frustrated Lewis Pair-Catalyzed Reactions

被引：49
|
作者：
Paradies, Jan [1 ]
机构：
[1] Univ Paderborn, Dept Chem, Warburger Str 100, D-33098 Paderborn, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 2019卷 / 2-3期
关键词：
Frustrated Lewis pair; Hydrogen activation; Hydrogenation; Lewis acids; Lewis bases; Protodeborylation; HETEROLYTIC DIHYDROGEN ACTIVATION; ELECTROPHILIC PHOSPHONIUM CATIONS; METAL-FREE HYDROGENATION; BOND ACTIVATION; STRUCTURAL FEATURES; ELECTRONIC CONTROL; LONDON DISPERSION; H-2; ACTIVATION; CHEMISTRY; CARBON;
D O I：
10.1002/ejoc.201800944
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review summarizes the principle reaction mechanisms of frustrated Lewis pairs (FLP) in hydrogenations and carbon-nitrogen and carbon-carbon bond forming reactions. The fundamental mechanism of hydrogen activation by FLPs is reviewed and the influence of the FLP's nature on hydrogenation reactions is discussed, leading to a structure-reactivity relationship in phosphine/borane or amine/borane derived FLPs. This reactivity concept is validated for a series of FLP-catalyzed reactions. Furthermore, alternative reaction mechanisms e.g. protodeborylations or sigma-bond metathesis are discussed.
引用
收藏
页码：283 / 294
页数：12
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