Kinetics and Mechanism of Electron Transfer Reactions: Oxidation of Crotyl Alcohol by Peroxomonosulfate in Aqueous Acidic Medium

被引：4
|
作者：
Sharma, Priyamvada [1 ]
Sailani, Riya [1 ]
Meena, Anita [2 ]
Khandelwal, C. L. [1 ]
机构：
[1] Univ Rajasthan, Dept Chem, Jaipur, Rajasthan, India
[2] Jai Narain Vyas Univ, Dept Chem, Jodhpur, Rajasthan, India
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 2018年 / 50卷 / 05期
关键词：
CHLORIDE CATALYZED OXIDATION; SELECTIVE OXIDATION; ACETATE BUFFERS; ASCORBIC-ACID; ION; DECOMPOSITION; COUPLE; ALLYL;
D O I：
10.1002/kin.21162
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics and mechanism of oxidation of crotyl alcohol by peroxomonosulfate has been studied, and the species of the peroxomonosulfate are discussed to find out the role of activated species. A plausible reaction mechanism is suggested, and a derived rate law corresponds to all experimental observations. The activation parameters such as energy and entropy of activation have been calculated as 37.21 +/- 0.5 kJ mol(-1) and -148.91 +/- 2.7 J K-1 mol(-1), respectively, by employing the Eyring plot.
引用
收藏
页码：335 / 342
页数：8
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