Anion binding with biphenyl-bis-urea derivatives: solution and solid-state studies

被引：3

作者：

Grguric, Toni ^{[1
]}

Cetina, Mario ^{[2
]}

Petroselli, Manuel ^{[3
]}

Bacchiocchi, Corrado ^{[4
]}

Dzolic, Zoran ^{[1
]}

Cametti, Massimo ^{[3
]}

机构：

[1] Rudjer Boskovic Inst, Bijenicka Cesta 54, Zagreb 10000, Croatia

[2] Univ Zagreb, Fac Text Technol, Dept Appl Chem, Prilaz Baruna Filipovica 28a, Zagreb 10000, Croatia

[3] Politecn Milan, Dept Chem Mat & Chem Engn Giulio Natta, Via Luigi Mancinelli 7, I-20131 Milan, Italy

[4] Univ Camerino, Div Chem, Sch Sci & Technol, Via S Agostino 1, I-62032 Camerino, MC, Italy

来源：

NEW JOURNAL OF CHEMISTRY | 2020年 / 44卷 / 38期

关键词：

RECOGNITION; FLUORIDE;

D O I：

10.1039/d0nj03670f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, we have synthesized and characterized bis-urea derivatives 1-3, featuring a biphenyl spacer, and studied their anion binding properties in DMSO solution and in the solid state. In solution, 1:1 complexes were observed with association constant K values in the 10(3)-10(4) M-1 range with a general preference for acetate over dihydrogenphosphate for all three receptors. We were also able to obtain and characterize, by X-ray diffraction on single crystals, ten receptor-anion complexes including acetate and dihydrogenphosphate, as well as monohydrogenphosphate, halides and the nitrate ion. Linear (anion-receptor)(n) arrays, porous frameworks and non-centrosymmetric structures were observed and described in detail.

引用

页码：16294 / 16301

页数：8

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