Mechanism of Reaction between Cobalt(II) Oxide and Ammonium Chloride

被引：7
|
作者：
Borisov, V. A. [1 ]
D'yachenko, A. N. [1 ]
Kraidenko, R. I. [1 ]
机构：
[1] Tomsk Natl Res Polytech Univ, Tomsk, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 57卷 / 07期
关键词：
10;
D O I：
10.1134/S0036023612070066
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A reaction between cobalt oxide and ammonium chloride was studied. A possible mechanism of this reaction was determined by TGA and DSC. The reaction products were identified by IR spectroscopy, chemical and XRD analyses. A multistage mechanism was established for reaction between cobalt oxide and ammonium chloride. Cobalt chloride was determined to be the final product; the reaction occurs via the formation and decomposition of (NH4)(3)CoCl5, (NH4)(2)CoCl4, and NH4CoCl3.
引用
收藏
页码：923 / 926
页数：4
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