Template-Free Synthesis of Hierarchical Porous Metal-Organic Frameworks

被引：189

作者：

Yue, Yanfeng ^{[1
]}

Qiao, Zhen-An ^{[1
]}

Fulvio, Pasquale F. ^{[1
]}

Binder, Andrew J. ^{[2
]}

Tian, Chengcheng ^{[2
]}

Chen, Jihua ^{[3
]}

Nelson, Kimberly M. ^{[2
]}

Zhu, Xiang ^{[2
]}

Dai, Sheng ^{[1
,2
]}

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[3] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 26期

关键词：

CARBON-DIOXIDE; ADSORPTION; MOLECULES; PLATFORM; SORPTION; SERIES; OXIDE;

D O I：

10.1021/ja402694f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of zinc(II) 2,5-dihydroxy-1,4-benzenedicarboxylate (Zn-MOF-74) is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with various synthesis solvents for different reaction times. This template-free strategy enables the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained in the synthesis of MOFs by the ligand-extension method.

引用

页码：9572 / 9575

页数：4

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