Heterogeneous Single-Molecule Diffusion in One-, Two-, and Three-Dimensional Microporous Coordination Polymers: Directional, Trapped, and Immobile Guests

被引：52
|
作者：
Liao, Yi [1 ]
Yang, Seong K. [1 ]
Koh, Kyoungmoo [1 ]
Matzger, Adam J. [1 ]
Biteen, Julie S. [1 ]
机构：
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源：
NANO LETTERS | 2012年 / 12卷 / 06期
关键词：
Microporous coordination polymer; single-molecule fluorescence microscopy; heterogeneous diffusion; single-particle tracking; cumulative probability distribution; PARTICLE TRACKING; MICROSCOPY; COPOLYMER; TRANSPORT;
D O I：
10.1021/nl300971t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The diffusion of individual Nile red molecules in three different crystalline microporous coordination polymers (MCPs) is visualized with single-molecule fluorescence microscopy. By localizing molecules with high spatial resolution, the trajectories of the diffusing dyes are reconstructed with nanometer-scale precision. A detailed analysis of these tracks reveals different dynamics and guest-host interactions in each crystal as well as distinct motion types within the same system, suggesting the presence of structural heterogeneities in local environments.
引用
收藏
页码：3080 / 3085
页数：6
相关论文
共 50 条
  • [1] One-, Two-, and Three-Dimensional Coordination Polymers of Stilbenedicarboxylate with Different Metal Ions
    Ma, Yu
    Cheng, Ai-Ling
    Zhang, Jian-Yong
    Yue, Qi
    Gao, En-Qing
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (02) : 867 - 873
  • [2] Reversible One- to Two- to Three-Dimensional Transformation in CuII Coordination Polymer
    Jing, Yao
    Yoshida, Yukihiro
    Huang, Pingping
    Kitagawa, Hiroshi
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (14)
  • [3] One-, Two-, and Three-Dimensional Hopping Dynamics
    Aoki, Keiko M.
    Fujiwara, Susumu
    Soga, Kiyoshi
    Ohnishi, Shuhei
    Yamamoto, Takenori
    [J]. CRYSTALS, 2013, 3 (02): : 315 - 332
  • [4] Combining one-, two- and three-dimensional polyphenylene nanostructures
    Wu, JS
    Grimsdale, AC
    Müllen, K
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (01) : 41 - 52
  • [5] MMN elicited by one-, two-, and three-dimensional deviants
    Wolff, C
    Schroger, E
    [J]. JOURNAL OF PSYCHOPHYSIOLOGY, 1995, 9 (04) : 384 - 385
  • [6] One-, two- and three-dimensional nanostructures with atom lithography
    Oberthaler, MK
    Pfau, T
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (06) : R233 - R255
  • [7] Inorganic crystal engineering through cation metathesis:: One-, two-, and three-dimensional cluster-based coordination polymers
    Zhou, Huajun
    Strates, Konstantia C.
    Munoz, Miguel A.
    Little, Kevin J.
    Pajerowski, Daniel M.
    Meisel, Mark W.
    Talham, Daniel R.
    Lachgar, Abdessadek
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (09) : 2238 - 2246
  • [8] The prediction of one-, two-, and three-dimensional heave in expansive soils
    Vu, HQ
    Fredlund, DG
    [J]. CANADIAN GEOTECHNICAL JOURNAL, 2004, 41 (04) : 713 - 737
  • [9] Performance in one-, two- and three-dimensional terminal aiming tasks
    Hoffmann, Errol R.
    Drury, Colin G.
    Romanowski, Carol J.
    [J]. ERGONOMICS, 2011, 54 (12) : 1175 - 1185
  • [10] One-, two- and three-dimensional interlocked polymers based on hybrid inorganic-organic rotaxanes
    Lockyer, Selena J.
    Whitehead, George F. S.
    Timco, Grigore A.
    McInnes, Eric J. L.
    Winpenny, Richard E. P.
    [J]. CHEMICAL COMMUNICATIONS, 2024, 60 (74) : 10124 - 10127
12345