Synthesis, Characterization, and Catalytic Activity of Cationic NHC Gold(III) Pyridine Complexes

被引：54
|
作者：
Orbisaglia, Serena [1 ,3 ]
Jacques, Beatrice [1 ]
Braunstein, Pierre [1 ]
Hueber, Damien [2 ]
Pale, Patrick [2 ]
Blanc, Aurelien [2 ]
de Fremont, Pierre [1 ]
机构：
[1] Univ Strasbourg, CNRS, Inst Chim, Lab Chim Coordinat,UMR 7177, F-67081 Strasbourg, France
[2] Univ Strasbourg, CNRS, Inst Chim, Lab Synthese React Organ & Catalyse,UMR 7177, F-67081 Strasbourg, France
[3] Univ Camerino, Sch Sci & Technol, I-62032 Camerino, MC, Italy
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 15期
关键词：
N-HETEROCYCLIC CARBENE; GOLD CATALYSIS; ORGANOGOLD(III) COMPLEXES; REACTIVITY; HYDROAMINATION; ALKYNES; OXYARYLATION; BEARING; LIGAND; FUNCTIONALIZATION;
D O I：
10.1021/om400338k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of cationic gold(I/III) pyridine complexes of the type [(L)Au(pyr)](PF6) and [(L)AuCl2(pyr)](PF6), where L = IPr, (1, 5); L = IMes (2, 6); L = (IBu)-Bu-t, (3, 7); L = ICy (4, 8); and L = PPh3, (9, 10), were synthesized and characterized by NMR spectroscopy and single-crystal X-ray diffraction. The stability of the new complexes and their catalytic activity in five well-established organic transformations were assessed.
引用
收藏
页码：4153 / 4164
页数：12
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