Synthesis and Crystal Structures of Two Copper(II) Complexes Containing Amide Type Ligands

被引：4
|
作者：
Cai Hong-Xin [1 ]
Wu Wei-Na [1 ]
Wang Yuan [1 ]
机构：
[1] Henan Polytech Univ, Dept Phys & Chem, Jiaozuo 454000, Henan, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 04期
关键词：
copper(II) complex; amide type ligand; crystal structure; LANTHANIDE COMPLEXES; LUMINESCENCE PROPERTIES; FLUORESCENT PROPERTIES;
D O I：
10.3969/j.issn.1001-4861.2013.00.121
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new complexes, [(CuL2Cl2)-Cl-1]DMF (1) and [(CuL2Cl2)-Cl-2] (2) (L-1=N-(4-chlorophenyl)-2-(quinolin-8-yloxy)acetamide, L-2=N,N-diphenyl-2-(quinolin-8-yloxy)acetamide), were synthesized and characterized by X-ray diffraction. In each complex, the six-coordinated Cu(II) ion is in a distored octahedral geometry with the donor centers of two O atoms and two N atoms from two ligands, and two chloride anions. In the crystal of 1, intramolecular N-H center dot center dot center dot Cl hydrogen bonds link the molecules into centrosymmetric dimers. However, there are no classic hydrogen bonds in the structure of 2. CCDC: 899968, 1; 854374, 2.
引用
收藏
页码：845 / 849
页数：5
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