Synthesis and structures of two luminescent Zn(II) complexes with pyrazole and carboxylate ligands

被引:66
|
作者
Li, J
Zhou, JH
Li, YZ
Weng, LH
Chen, XT [1 ]
Yu, Z
Xue, ZL
机构
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
zinc; pyrazole; betaine; crystal structure; luminescence;
D O I
10.1016/j.inoche.2004.02.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new Zn(II) complexes with pyrazole and carboxylate ligands, [Zn(mu-pz)(pzH)(O2CCH2CH3)](2) (pzH = pyrazole), 1 and [Zn(bet)(2)(pzH)(2)](ClO4)(2) (bet = Me3NCH2CO2), 2, were prepared and structurally characterized. Both compounds exhibit blue emission at room temperature in solid state. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:538 / 541
页数:4
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