HClO4-SiO2 as an Efficient and Reusable Heterogeneous Catalyst for the Synthesis of 1-substituted Tetrazoles

被引：7

作者：

Bahari, Siavash ^{[1
]}

Rezaei, Akbar ^{[1
]}

机构：

[1] Islamic Azad Univ, Ahar Branch, Dept Chem, Ahar, Iran

来源：

LETTERS IN ORGANIC CHEMISTRY | 2014年 / 11卷 / 01期

关键词：

Primary amines; triethyl orthoformate; 1-substituted 1H-1,2,3,4-tetrazole; HClO4-SiO2; heterogeneous catalyst; SUPPORTED PERCHLORIC-ACID; NATROLITE ZEOLITE; HIGHLY EFFICIENT; GREEN SYNTHESIS; SILICA; NITRILES; 1H-1,2,3,4-TETRAZOLES; ELECTROLUMINESCENCE; FECL3-SIO2; REAGENT;

D O I：

10.2174/157017861101140113161526

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and direct protocol is described for the preparation of 1-substituted 1H-1,2,3,4-tetrazoles by the reaction of primary amines, triethyl orthoformate and sodium azide in the presence of catalytic amount of silica-supported perchloric acid under solvent-free and heterogeneous conditions. The thermal solvent-free green procedure offers advantages such as simple methodology, easy work-up, high yield, recovery and reusability of catalyst.

引用

页码：55 / 58

页数：4

共 50 条

[1] Silica supported perchloric acid (HClO4-SiO2): A mild, reusable and highly efficient heterogeneous catalyst for the synthesis of amidoalkyl naphthols
Mahdavinia, Gholam Hossein
Bigdeli, Mohammad A.
Heravi, Majid M.
CHINESE CHEMICAL LETTERS, 2008, 19 (10) : 1171 - 1174
[2] Silica supported perchloric acid(HClO4-SiO2):A mild,reusable and highly efficient heterogeneous catalyst for the synthesis of amidoalkyl naphthols
Gholam Hossein Mahdavinia
Mohammad A.Bigdeli
Majid M.Heravi
Chinese Chemical Letters, 2008, (10) : 1171 - 1174
[3] HClO4-SiO2 AS AN EFFICIENT AND RECYCLABLE CATALYST FOR THE SYNTHESIS OF AMIDE DERIVATIVES
Song, Weibin
Ma, Lei
Hu, Lihong
SYNTHETIC COMMUNICATIONS, 2011, 41 (21) : 3186 - 3196
[4] Synthesis of bioactive heterocycles using reusable heterogeneous catalyst HClO4-SiO2 under solvent-free conditions
Chanu, Leimajam Vartima
Singh, Thokchom Prasanta
Devi, Laishram Ronibala
Singh, Okram Mukherjee
GREEN CHEMISTRY LETTERS AND REVIEWS, 2018, 11 (03) : 352 - 360
[5] Silica Supported Perchloric Acid (HClO4-SiO2): Highly Efficient Heterogeneous Catalyst for the Synthesis of α-Amino Phosphonates
Rostamizadeh, Mohsen
Maghsoodlou, Malek T.
Hazeri, Nourallah
Habibi-Khorassani, Sayyed M.
Sajadikhah, Seyed S.
Maleki, Nariman
Shahkarami, Zahra
LETTERS IN ORGANIC CHEMISTRY, 2010, 7 (07) : 542 - 544
[6] Synthesis of 2,3-Dihydro-4-pyridones Using HClO4-SiO2 or NaHSO4-SiO2 as an Efficient Heterogeneous Catalyst
Wu, Liqiang
Yang, Limin
Yan, Fulin
ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (09) : 6977 - 6982
[7] HClO4-SiO2 as a new, highly efficient, inexpensive and reusable catalyst for N-tert-butoxycarbonylation of amines
Chakraborti, Asit K.
Chankeshwara, Sunay V.
ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (14) : 2769 - 2771
[8] Synthesis of 1-substituted Tetrazoles Using CoFe2O4 Nanoparticles as a Magnetically Recoverable and Reusable Catalyst
Bahari, Siavash
LETTERS IN ORGANIC CHEMISTRY, 2013, 10 (07) : 527 - 531
[9] HClO4-SiO2: An Efficient Reusable Catalyst for the Synthesis of 3,4,5-Trisubstituted 1,2,4-Triazoles Under Solvent-Free Conditions
Vidavalur Siddaiah
Gajula Mahaboob Basha
Rayavarapu Srinuvasarao
Santosh Kumar Yadav
Catalysis Letters, 2011, 141 : 1511 - 1520
[10] HClO4-SiO2: An Efficient Reusable Catalyst for the Synthesis of 3,4,5-Trisubstituted 1,2,4-Triazoles Under Solvent-Free Conditions
Siddaiah, Vidavalur
Basha, Gajula Mahaboob
Srinuvasarao, Rayavarapu
Yadav, Santosh Kumar
CATALYSIS LETTERS, 2011, 141 (10) : 1511 - 1520

← 1 2 3 4 5 →