Giant optical activity in quasi-2D planar nanostructures

Planar chirality can lead to interesting polarization effects whose interpretation has invoked possible violation of reciprocity and time reversality. We show that a quasi-two-dimensional array consisting of gold nanoparticles with no symmetry plane and having sub-wavelength periodicity and thickness exhibits giant specific rotation (similar to 10(4) degrees/mm) at normal incidence. The rotation is the same for light incident on the front and back sides of the sample. Such reciprocity manifests three-dimensionality of the structure arising from the asymmetry of light-plasmon coupling at the air-metal and substrate-metal interfaces of the structure. The structures thus enable nanoscale polarization control but violate no symmetry principle.