The Au(III)-catalyzed coupling reactions between alcohols and N-heterocycles via C-H bond activation

被引：24
|
作者：
Jiang, Honglai [1 ]
Xie, Jin [1 ]
Lin, Aijun [1 ]
Cheng, Yixiang [1 ]
Zhu, Chengjian [1 ,2 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
来源：
RSC ADVANCES | 2012年 / 2卷 / 28期
基金：
中国国家自然科学基金;
关键词：
FREE-RADICAL REACTIONS; TRANSFER HYDROGENATION; CATALYSIS; OXIDATION; ACYLATION; OXYGEN;
D O I：
10.1039/c2ra22120a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel and highly efficient dehydrogenative C-C coupling between sp(3) C-H and sp(2) C-H bonds catalyzed by gold has been developed using environmentally benign tert-butyl hydroperoxide as oxidant. This new methodology provides a facile access to acylate N-heterocycles.
引用
收藏
页码：10496 / 10498
页数：3
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