Recovery and purification of plutonium in lean plutonium product stream obtained during reprocessing of fast reactor spent fuels

被引:1
|
作者
Govindan, P. [1 ]
Vijayan, K. S. [1 ]
Kumar, G. Santhosh [1 ]
Vijayakumar, V. [1 ]
Venkataraman, M. [1 ]
Natarajan, R. [1 ]
机构
[1] Indira Gandhi Ctr Atom Res, Reproc Grp, Reproc Plant Operat Div, Kalpakkam 603102, Tamil Nadu, India
关键词
Anion exchange resin; Dowex 1X4 (50-100 mesh); Decontamination factor; Pre-concentration; Precipitation; ANION-EXCHANGE; TECHNOLOGY;
D O I
10.1007/s10967-012-2194-z
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A method has been developed for final purification of plutonium from uranium and fission products of high beta gamma activity. This method involves selection of a suitable ion exchange resin for the purification of plutonium in order to deliver a quality PuO2 product. The effect of the concentration of uranium and plutonium, effect of increased loading of uranium and number of bed volumes for effective washing, which are some of the parameters that generally affect the recovery and purification of plutonium were investigated. An excellent decontamination factor for fission products has been achieved by this anion exchange process which in turn delivered an excellent PuO2 product quality in terms of purity and associated beta gamma activity with low personnel radiation exposure.
引用
收藏
页码:307 / 313
页数:7
相关论文
共 47 条
  • [1] Recovery and purification of plutonium in lean plutonium product stream obtained during reprocessing of fast reactor spent fuels
    P. Govindan
    K. S. Vijayan
    G. Santhosh Kumar
    V. Vijayakumar
    M. Venkataraman
    R. Natarajan
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2013, 295 : 307 - 313
  • [2] Purification and recovery of plutonium from uranium oxide obtained in the fast reactor fuel reprocessing plant using hydroxyurea as reductant
    P. Sivakumar
    S. Meenakshi
    R. V. Subba Rao
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2012, 291 : 763 - 767
  • [3] Purification and recovery of plutonium from uranium oxide obtained in the fast reactor fuel reprocessing plant using hydroxyurea as reductant
    Sivakumar, P.
    Meenakshi, S.
    Rao, R. V. Subba
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2012, 291 (03) : 763 - 767
  • [4] MEASURING PLUTONIUM HOMOGENEITY IN FAST REACTOR FUELS
    AITKEN, EA
    EVANS, SK
    ROSENBAU.HS
    WADEKAMP.DC
    [J]. TRANSACTIONS OF THE AMERICAN NUCLEAR SOCIETY, 1970, 13 (02): : 602 - &
  • [5] REPROCESSING OF PLUTONIUM-ENRICHED LIGHT WATER-REACTOR FUELS
    DETILLEUX, EJ
    HILD, W
    GEENS, L
    [J]. NUCLEAR TECHNOLOGY, 1983, 61 (03) : 398 - 402
  • [6] THERMODYNAMICS OF PLUTONIUM AND URANIUM IN LIQUID ALLOYS AND APPLICATION TO PYROCHEMICAL REPROCESSING OF FAST BREEDER REACTOR-FUELS
    JOHNSON, I
    [J]. JOURNAL OF NUCLEAR MATERIALS, 1974, 51 (01) : 163 - 177
  • [7] Optimization of Flowsheet for Scrubbing of Ruthenium during the Reprocessing of Fast Reactor Spent Fuels
    Natarajan, R.
    Dhamodharan, K.
    Sharma, Pradeep Kumar
    Pugazhendi, S.
    Vijayakumar, V.
    Pandey, N. K.
    Rao, R. V. Subba
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 2013, 48 (16): : 2494 - 2498
  • [8] REPROCESSING PLUTONIUM REACTOR FUEL - REMOVAL OF FISSION PRODUCT ELEMENTS BY SLAGGING
    MULLINS, LJ
    LEARY, JA
    MARAMAN, WJ
    [J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1960, 52 (03): : 227 - 230
  • [9] Properties of plutonium and its alloys for use as fast reactor fuels
    Hecker, Siegfried S.
    Stan, Marius
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2008, 383 (1-2) : 112 - 118
  • [10] FISSION PRODUCT HEATING IN FAST REACTOR PLUTONIUM FUEL
    BATTAT, ME
    DUDZIAK, DJ
    JOHNSTON, K
    [J]. JOURNAL OF NUCLEAR ENERGY, 1968, 22 (11): : 703 - &