Peculiarities of defect formation processes in ZnSe crystals with isovalent Te impurity

被引:1
|
作者
Makhniy, VP
Tkachenko, IV
Gorley, PM [2 ]
Horley, PP
Dugaev, VK
Barnas, J
Vieira, MM
Dobrowolski, W
机构
[1] Yuri Fedkovych Chernivtsi Natl Univ, Dept Opt Elect, 2 Kotsyubynsky Str, UA-58012 Chernovtsy, Ukraine
[2] Yuri Fedkovych Chernivtsi Natl Univ, Dept Elect & Energy Engn, 2 Kotsyubynsky Str, UA-58012 Chernovtsy, Ukraine
[3] Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, UA-58001 Chernovtsy, Ukraine
[4] Inst Super Tecn, CFIF, Dept Phys, P-1049001 Lisbon, Portugal
[5] Adam Mickiewicz Univ, Polish Acad Sci, Inst Mol Phys, Dept Phys, PL-60179 Poznan, Poland
[6] Inst Super Engn Lisboa, Dept Elect & Commun, P-1049001 Lisbon, Portugal
[7] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
关键词
D O I
10.1002/pssc.200564708
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Using quasi-chemical reaction methods, we calculated concentrations of equilibrium defects for zinc selenide crystals doped with ZnSe < Te > during the growth process and with ZnSe:Te from the vapour phase. It was found that the main irradiation peak at h omega(m) approximate to 1.7 eV for ZnSe < Te > samples is defined with the associates formed by single-charge intrinsic defects - positive interstitial zinc atoms Zn-i(*) and its negative vacancies V'(Zn). These vacancies, reaching the concentrations of 10(22) cm(-3) in ZnSe:Te crystals, are also responsible for the luminescence and absorption peaks at the energies of 2.4 eV.
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收藏
页码:829 / +
页数:2
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