Calorimetric study of cationic photopolymerization

被引：2
|
作者：
Czajlik, I
Hedvig, P
Ille, A
Dobo, J
机构：
[1] Plast. Research and Development Ltd., Budapest H-1143
来源：
RADIATION PHYSICS AND CHEMISTRY | 1996年 / 47卷 / 03期
基金：
匈牙利科学研究基金会;
关键词：
D O I：
10.1016/0969-806X(95)00140-S
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photopolymerization of penta-erythritol tetra-glycidyl ether (initiator Degacure KI-85) was studied by a du Pont 910 type DSC. From our experimental results the following conclusions can be drawn: (1) During the cationic polymerization reaction the lifetime of the initiating centers are long compared to the lifetime of free radicals in case of radical polymerization. (2) The rate of deactivation of the initiating centers increases with increasing temperature.
引用
收藏
页码：453 / 455
页数：3
相关论文
共 50 条
  • [1] Study on cationic photopolymerization reaction of epoxy polysiloxane
    Sun, F.
    Jiang, S. L.
    Liu, J.
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2007, 264 (02): : 318 - 322
  • [2] Study of the cationic photopolymerization kinetics of cyclic acetals
    Magdalena Pantiru
    Dumitru Mircea Vuluga
    Dan Sorin Vasilescu
    Marc J. M. Abadie
    Polymer Bulletin, 2002, 47 : 485 - 492
  • [3] Study of the cationic photopolymerization kinetics of cyclic acetals
    Pantiru, M
    Vuluga, DM
    Vasilescu, DS
    Abadie, MJM
    POLYMER BULLETIN, 2002, 47 (05) : 485 - 492
  • [4] Cationic Aerosol Photopolymerization
    Akguen, Ertan
    Muntean, Alex
    Hubbuch, Juergen
    Woerner, Michael
    Sangermano, Marco
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2015, 300 (02) : 136 - 139
  • [5] Advances in cationic photopolymerization
    Sangermano, Marco
    PURE AND APPLIED CHEMISTRY, 2012, 84 (10) : 2089 - 2101
  • [6] Interaction of DNA with cationic vesicles: A calorimetric study
    Barreleiro, PCA
    Olofsson, G
    Alexandridis, P
    JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (32): : 7795 - 7802
  • [7] STUDY OF THE CATIONIC PHOTOPOLYMERIZATION OF MULTIFUNCTIONAL PROPENYL ETHER MONOMERS
    CRIVELLO, JV
    BRATSLAVSKY, SA
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1994, A31 (12): : 1927 - 1941
  • [8] Study on cationic and hybrid photopolymerization systems used in stereolithgraphy
    Meng, Huaidong
    Yin, Jinxiang
    Lin, Tianshu
    Hong, Xiaoyin
    Fushe Yanjiu yu Fushe Gongyi Xuebao/Journal of Radiation Research and Radiation Processing, 2000, 18 (01): : 19 - 24
  • [9] KINETIC-STUDY OF THE CATIONIC PHOTOPOLYMERIZATION OF EPOXY MONOMERS
    DECKER, C
    MOUSSA, K
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (12) : 3429 - 3443
  • [10] New Horizons in Cationic Photopolymerization
    Sangermano, Marco
    Roppolo, Ignazio
    Chiappone, Annalisa
    POLYMERS, 2018, 10 (02):
12345