Radiolytically prepared poly(vinyl alcohol) hydrogel containing α-cyclodextrin

被引:5
|
作者
Yamamoto, Y [1 ]
Tagawa, S [1 ]
机构
[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan
关键词
cyclodextrin; poly(vinyl alcohol); hydrogel; inclusion complexation;
D O I
10.1016/j.radphyschem.2003.08.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
a-Cyclodextrin (alpha-CD) was immobilized by the radiation-induced gelation of poly(vinyl,alcohol) (PVA). An aqueous solution of 4-nitrophenol (4-Np) was added upon the PVA hydrogel containing alpha-CD in a quartz cell. Absorption spectra of the hydrogel phase have demonstrated that 4-Np permeates into the hydrogel and is included by alpha-CD. When pure toluene was added upon the hydrogel, the rate of the permeation of toluene was affected by the inclusion complexation with alpha-CD. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:347 / 349
页数:3
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